An Unprecedented Tridentate-Bridging Coordination Mode of Permanganate Ions: the Synthesis of an Anionic Coordination Polymer—[CoIII(NH3)6]n[(K(κ1-Cl)2(μ2,2′,2″-(κ3-O,O′,O″-MnO4)2)n∞]—Containing Potassium Central Ion and Chlorido and Permanganato Ligands
MOLECULES(2024)
Key words
chlorido and permanganato ligands,hexaamminecobalt(III),coordination polymer,tridentate permanganate,crystal structure,hydrogen bond,resonance Raman effect,cobalt manganite spinel,thermal decomposition,nanocrystallites
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